The Irving-William series:
This series is obtained from a plot of long
Kf against Z for the first-row transition elements. For any one set of
ligands, i.e., no change in ligand type, the series shows a regular
increase in stability constants from Sc to Cu, and a decrease to
zinc.
Ba2+ < Sr2+ <
Ca2+< Mg2+ < Mn2+ < Fe2+
< Co2+ < Ni2+ < Cu2+ > Zn2+
This series can be understood as a consequence
of electrostatic effects, of the first part of this series. Ligand-field
interactions explain the increase in the value of Kf for Fe (II),
d6; Co (II), d7; Ni (II), d8; and Cu (II),
d9 – Cu (II) obtains increased stability from Jahn-Teller
distortion when compared to Ni (II) complexes.
Stability of metal complexes with reference to the nature of ligand:
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For detail study Click on these links:
1- http://web.uvic.ca/~djberg/Chem324/Chem324-14.pdf
2 -http://bit.ly/10OzNcK (Important Link)
Stability of metal complexes with reference to the nature of ligand:
For detail study Click on these links:
1- http://web.uvic.ca/~djberg/Chem324/Chem324-14.pdf
2 -http://bit.ly/10OzNcK (Important Link)
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